Inverse Martensitic Transformation in Zr Nanowires

Loading...
Thumbnail Image
Penn collection
Departmental Papers (MSE)
Degree type
Discipline
Subject
Engineering
Materials Science and Engineering
Funder
Grant number
License
Copyright date
Distributor
Related resources
Author
Li, Suzhi
Ding, Xiangdong
Ren, Xiaobing
Sun, Jun
Ma, Evan
Lookman, Turab
Contributor
Abstract

Like martensitic transformations (MTs), inverse martensitic transformations (IMTs) are shear-dominant diffusionless transformations, but are driven by reduction in interfacial energies rather than bulk free energies, and exhibit distinctive behavior such as instantaneous initiation (like spinodal decomposition) and self-limiting lengthscale. Bulk Zr metal is known to undergo normal MT from the high-temperature bcc phase to the low-temperature hcp phase. Using molecular dynamics simulations we demonstrate that, unlike in the bulk, an IMT to the bcc structure can occur in (1100)-oriented hcp Zr nanowires at low temperatures, which is driven by the reduction in the nanowire surface energy. The bcc domains subsequently become distorted and transform into a new (1120)-oriented hcp domain, leading to reorientation of the nanowire. This behavior has implications for the study of structural transformations at the nanoscale and surface patterning.

Advisor
Date Range for Data Collection (Start Date)
Date Range for Data Collection (End Date)
Digital Object Identifier
Series name and number
Publication date
2010-01-01
Journal title
Volume number
Issue number
Publisher
Publisher DOI
Journal Issue
Comments
Suggested Citation: Li, S. Z, Ding, J. Li, X. Ren, et. al. "Inverse martensitic transfromation in Zr nanowires." Physical Review B Vol. 81, 245433. © American Physical Society http://dx.doi.org/10.1103/PhysRevB.81.245433
Recommended citation
Collection