Theoretical Analysis of Inelastic Neutron Scattering in Solid Hydrogen

Loading...
Thumbnail Image
Penn collection
Department of Physics Papers
Degree type
Discipline
Subject
Physics
Quantum Physics
Funder
Grant number
License
Copyright date
Distributor
Related resources
Author
Berlinsky, A. John
Contributor
Abstract

The inelastic-neutron-scattering cross section of (J=1) solid hydrogen is studied and the experimental data of Stein and co-workers analyzed. The rms displacement ⟨u2⟩1/2 is deduced from the data via different methods and mutually consistent values of order 0.65 Å are obtained. The enhancement of the cross section at the libron energy due to libron-phonon interactions is found to be the same, about 40% each for both one-and two-libron processes, in agreement with the neutron scattering data. The rms splitting at the libron-phonon crossovers is found to be about 1 cm−1, somewhat smaller than found by Mertens and Biem. A sum rule for the J=1 to J=0 cross section is given which relates the average energy of this transition to the orientational internal energy. Using high-temperature expansions and experimental data for the specific heat, we obtain a qualitative fit to the neutron scattering data in the orientationally disordered phase. In the ordered phase both the sum rule and a direct calculation indicate the existence of a libron sideband above the main J=1 to J=0 line having an intensity of 10% of the main line. The energy of the main line at zero temperature is calculated including (a) tipping corrections, (b) virtual excitations with J not conserved, and (c) modified zero-point energy. The value of the electrostatic quadrupole-quadrupole coupling constant deduced from the data of Stein and co-workers using this calculation is in agreement with that obtained from other experiments.

Advisor
Date Range for Data Collection (Start Date)
Date Range for Data Collection (End Date)
Digital Object Identifier
Series name and number
Publication date
1977-10-15
Journal title
Physical Review B
Volume number
Issue number
Publisher
Publisher DOI
Journal Issue
Comments
Recommended citation
Collection