Departmental Papers (EES)
The mission of our department is to bring the time perspective of the Earth scientist to bear on contemporary problems of natural-resource conservation and environmental quality. We pursue this mission by exploring present and past interactions of processes that integrate the four terrestrial spheres: lithosphere, hydrosphere, atmosphere, and biosphere; by reconstructing the physical and biological history of our planet to provide a baseline for projection of observed trends into an uncertain future; and by educating future generations of environmental analysts, managers, and planners to exercise responsible stewardship of Earth and her natural resources.
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Publication Magnetite in the Human Body: Biogenic vs. Anthropogenic(2016-10-01) Gieré, RetoMagnetite is an iron-oxide mineral that occurs naturally on Earth. Because it is also an important component of many anthropogenic materials (e.g., coal fly ash) and synthetic products (e.g., black toner powders), magnetite can be released to the environment through human activities (1). In PNAS,Maher et al. (2) describe the abundant presence in the human brain of magnetite nanoparticles, some of which they attribute to air pollution. This finding could have major implications.Publication The Role of Th-U Minerals in Assessing the Performance of Nuclear Waste Forms(2014-10-01) Lumpkin, Gregory R; Gao, Yan; Gieré, Reto; Williams, C T; Mariano, Anthony; Geisler, ThorstenMaterials designed for nuclear waste disposal include a range of ceramics, glass ceramics and glass waste forms. Those with crystalline phases have provided the momentum for studies of minerals as a means to understand aspects of waste-form crystal chemistry, behaviour in aqueous systems and radiation damage over geological periods of time. Although the utility of natural analogue studies varies, depending upon the degree of analogy to the proposed geological repository and other factors such as chemical composition, the available data suggest that Th-U host phases such as brannerite, monazite, pyrochlore, zircon and zirconolite are resistant generally to dissolution in aqueous fluids at low temperatures. Geochemical durability may or may not extend to hydrothermal systems depending on the specifics of fluid composition, temperature and pressure. At elevated temperatures, for example, davidite may break down to new phase assemblages including titanite, ilmenite and rutile. Perovskite is generally less resistant to dissolution at low temperatures and breaks down to TiO2, releasing A-site cations to the aqueous fluid. Studies of radiation damage indicate that the oxide and silicate phases become amorphous as a result of the gradual accumulation of alpha-recoil collision cascades. Monazite tends to remain crystalline on geological time scales, a very attractive property that potentially eliminates major changes in physical properties such as density and volume, thereby reducing the potential for cracking, which is a major concern for zircon. In spite of recent success in describing the behaviour of Th-U minerals in geological systems, considerable work remains in order to understand the P-T-X conditions during alteration and T-t history of the host rocks.Publication Recalcitrant Pharmaceuticals in the Aquatic Environment: A Comparative Screening Study of Their Occurrence, Formation of Phototransformation Products and Their in Vitro Toxicity(2014-01-01) Bergheim, Marlies; Gminski, Richard; Spangenberg, Bernd; Dębiak, Malgorzata; Bürkle, Alexander; Mersch-Sundermann, Volker; Kümmerer, Klaus; Gieré, RetoData allowing for a complete environmental risk assessment of pharmaceuticals and their photoderatives in the environment are still scarce. In the present study, in vitro toxicity and both bio- and photopersistence of various pharmaceuticals (aciclovir, allopurinol, cetirizine, cimetidine, fluconazole, hydrochlorothiazide, lisinopril, phenytoin, primidone, ranitidine, sotalol, sulpiride, tramadol and valsartane) as well as their phototransformation products were evaluated in order to fill data gaps and to help prioritise them for further testing. Twelve out of the fourteen compounds investigated were found to be neither readily nor inherently biodegradable in the Organisation of Economic Cooperation and Development-biodegradability tests. The study further demonstrates that the photo-induced transformation of the pharmaceuticals was faster upon irradiation with a Hg lamp (UV light) than with a Xe lamp emitting a spectrum that mimics sunlight. Comparing the non-irradiated with the respective irradiated solutions, a higher acute and chronic toxicity against bacteria was found for the irradiated solutions of seven compounds (cetirizine, cimetidine, hydrochlorothiazide, ranitidine, sulpiride, tramadol and valsartane). No cyto- and genotoxic effects were found in human cervical (HeLa) and liver (Hep-G2) cells for any of the investigated compounds or their phototransformation products. This comparative study documents that phototransformation products can arise as a result of UV treatment of wastewater containing these pharmaceuticals. It further demonstrates that some phototransformation products may have a higher environmental risk potential than the respective parent compounds because some phototransformation products exhibited a higher bacterial toxicity.Publication REE Zoning in Allanite Related to Changing Partition Coefficients During Crystallization: Implications for REE Behaviour in an Epidote-Bearing Tonalite(2006-08-01) Beard, J S; Sorensen, S S; Gieré, RetoAllanite is present in most samples of the tonalitic Bell Island Pluton, with an average mode near 0.05 wt.%. Allanite occurs as cores in igneous epidote-clinozoisite and exhibits characteristic and consistent zoning patterns. REE-rich cores (All40–70) grade out towards epidote-clinozoisite with REE below electron microprobe detection limits. La, Ce and Pr contents are highest in the REE-rich cores of zoned crystals. Nd and Sm contents both initially increase as total REE decreases and are highest in intermediate zones. Y contents are generally low throughout, but tend to be highest in analyses with All5–20. The zoning behaviour exhibited by the allanite, specifically the rimward increases in Nd, Sm, and Y, cannot be accounted for by simple fractionation and are best explained by increases in allanite/melt partition coefficients (Kd values) for these elements during crystallization. We propose that the variation in Kd values reflects modification of the allanite structure with changing REE content. These modifications are manifested by changes in colour, extinction, and pleochroism within the zoned crystals and include changes in unit-cell volume and dimensions. The changes in Kd values are large enough to result in crossing REE patterns within single allanite crystals. Fractional crystallization of zoned allanite can have noticeable effects on LREE contents and La/Sm (and almost certainly La/Lu) in magmas. In the Bell Island pluton, 80% of La, but <3% of Y is contained in allanite. Although some of the variation in the LREE chemistry of the pluton is attributable to statistical sampling error, much of it appears to reflect petrogenetic processes that controlled LREE abundance and, ultimately, allanite mode. One sample of Bell Island tonalite is depleted in LREE and has low La/Lu and La/Sm. These chemical features can be modelled by fractionation of zoned allanite.Publication Zirconolite: A Review of Localities Worldwide, and a Compilation of its Chemical Compositions(1996-06-01) Williams, C T; Gieré, RetoA compilation of the chemical data and brief review of the mineral zirconolite, essentially CaZrTi207, is presented. A total of 321 chemical analyses, 169 previously unpublished, from 39 of the 46 known terrestrial localities, and covering IO rock types are tabulated. A brief description of the minerals associated with zirconolite is outlined for each locality. Data from all zirconolite-bearing lunar rocks have also been compiled. The recently published nomenclature scheme for zirconolite is employed throughout.Publication Retention of Actinides in Natural Pyrochlores and Zirconolites(1994) Lumpkin, Gregory R; Hart, K P; McGlinn, P J; Payne, T E; Gieré, Reto; Williams, C TNatural pyrochlore and zirconolite undergo a crystalline-aperiodic transformation caused by alpha-decay of 232Th and 2380 at dose levels between 2 X 1014 and 3 X 1017 a/mg. The principal effects of the transformation are volume expansion and microfracturing, providing potential pathways for fluids. Geochemical alteration of the minerals may occur under hydrothermal conditions or in low temperature, near surface environments, but Th and U usually remain immobile and can be retained for time scales up to 109 years. However, the Th-U isotope systematics of a zirconolite-bearing vein and dolomite host rock may provide evidence for disequilibrium between 230Th, 234U and 238U.Publication The Pulse of Calm Fan Deltas(2008-07-01) Kim, Wonsuck; Jerolmack, Douglas JAt the heart of interpreting the history of Earth surface evolution preserved in the rock record is distinguishing environmental (allogenic) forcing from internally generated (autogenic) “noise.” Allogenic deposits classically have been recognized by their cyclic nature, which apparently results from periodic changes in base level, sediment supply, or tectonics. Autogenic deposits, which are quite variable in their origin and scale, are caused by the nonlinearity of sediment transport and might be expected to have a random or scale-free (fractal) signature. Here we describe a robust mechanism that generates cyclic deposits by an autogenic process in experimental fan deltas. Sheet flow over the fan surface induces deposition and an increase in fluvial slope and curvature to a point where the surface geometry is susceptible to a channelization instability, similar to channel initiation on hillslopes. Channelized flow results in incision and degrading of the fan surface to a lower slope, releasing a pulse of sediment that pushes the shoreline forward. Sheet flow resumes once the surface is regraded, and the cycle repeats in a surprisingly periodic fashion to produce cyclic foreset accretions. We use simple scaling and a one-dimensional fan evolution model to (1) demonstrate how time-varying flow width can cause pulses in sediment discharge at the shoreline in agreement with experiments and (2) reinterpret cyclic deposits reported in the field. Alternating sheet and channelized flows are known to operate on noncohesive fans in nature. Our results suggest that rather than reflecting variation in environmental forcing, many observed cyclic sedimentation packages may be a signature of the autogenic “pulse” of fan deltas under calm environmental conditions.Publication Diffusive Evolution of Experimental Braided Rivers(2014-05-01) Reitz, Meredith D; Jerolmack, Douglas J; Lajeunesse, Eric; Limare, Angela; Devauchelle, Olivier; Métivier, FrançoisWater flowing over a loose granular bed organizes into a braided river, a network of ephemeral and interacting channels. The temporal and spatial evolution of this network of braided channels is not yet quantitatively understood. In ∼1 m-scale experiments, we found that individual channels exhibit a self-similar geometry and near-threshold transport conditions. Measurements of the rate of growth of topographic correlation length scales, the time scale of system-slope establishment, and the random spatial decorrelation of channel locations indicate together that the evolution of the braided river system may be diffusive in nature. This diffusion is due to the separation of scales between channel formation and network evolution, and the random motion of interacting channels when viewed at a coarse-grained scale.Publication Dynamics and Mechanics of Bed-Load Tracer Particles(2014-12-19) Phillips, Colin B; Jerolmack, Douglas JUnderstanding the mechanics of bed load at the flood scale is necessary to link hydrology to landscape evolution. Here we report on observations of the transport of coarse sediment tracer particles in a cobble-bedded alluvial river and a step-pool bedrock tributary, at the individual flood and multi-annual timescales. Tracer particle data for each survey are composed of measured displacement lengths for individual particles, and the number of tagged particles mobilized. For single floods we find that measured tracer particle displacement lengths are exponentially distributed; the number of mobile particles increases linearly with peak flood Shields stress, indicating partial bed load transport for all observed floods; and modal displacement distances scale linearly with excess shear velocity. These findings provide quantitative field support for a recently proposed modeling framework based on momentum conservation at the grain scale. Tracer displacement is weakly negatively correlated with particle size at the individual flood scale; however cumulative travel distance begins to show a stronger inverse relation to grain size when measured over many transport events. The observed spatial sorting of tracers approaches that of the river bed, and is consistent with size-selective deposition models and laboratory experiments. Tracer displacement data for the bedrock and alluvial channels collapse onto a single curve – despite more than an order of magnitude difference in channel slope – when variations of critical Shields stress and flow resistance between the two are accounted for. Results show how bed load dynamics may be predicted from a record of river stage, providing a direct link between climate and sediment transport.Publication Origin of Hysteresis in Bed Form Response to Unsteady Flows(2013-03-01) Martin, Raleigh L; Jerolmack, Douglas JField and laboratory studies indicate that changes in riverbed morphology often lag changes in water discharge. This lagged response produces hysteresis in the relationship between water discharge and bed form geometry. To understand these phenomena, we performed flume experiments to observe the response of a sand bed to step increases and decreases in water discharge. For an abrupt rise in discharge, we observed that bed forms grew rapidly by collision and merger of bed forms migrating with different celerities. Growth rate slowed as bed forms approached equilibrium with the higher discharge regime. After an abrupt discharge drop, bed form decay occurred through formation of smaller secondary bed forms, in equilibrium with the lower discharge, which cannibalized the original, relict features. We present a simple model framework to quantitatively predict time scales of bed form adjustment to flow changes, based on equilibrium bed form heights, lengths, and celerities at low and high flows. For rising discharge, the model assumes that all bed form collisions result in irreversible merger, due to a dispersion of initial celerities. For falling discharge, we derive a diffusion model for the decay of relict high-stage features. Our models predict the form and time scale of experimental bed form adjustments. Additional experiments applying slow and fast triangular flood waves show that bed form hysteresis occurs only when the time scale of flow change is faster than the modeled (and measured) bed form adjustment time. We show that our predicted adjustment time scales can also be used to predict the occurrence of bed form hysteresis in natural floods.