New Phosgene-Free Route to Polycarbonates

Loading...
Thumbnail Image
Penn collection
Senior Design Reports (CBE)
Degree type
Discipline
Subject
Biochemical and Biomolecular Engineering
Chemical Engineering
Engineering
Funder
Grant number
License
Copyright date
Distributor
Related resources
Author
Castro, Federico
Jablansky, Abigail
Lee, Heui Beom
MacMillan, Imran
Contributor
Abstract

A process to produce 100 million pounds per year of diphenyl carbonate (DPC) based on the phosgene-free oxidative carbonylation of phenol in US Patent 8,212,066 has been designed. In this reaction, phenol reacts directly with carbon monoxide in the presence of a palladium catalyst, an organic co-catalyst or ligand, a redox catalyst, and a base catalyst. The proposed design features a single-reactor system followed by a separation train that includes a vacuum distillation tower, and it produces only water and carbon monoxide as byproducts. Detailed process and unit descriptions, an in- depth economic analysis, and environmental concerns and other considerations are also included. The net present value of this project was determined to be $51,560,200 with a return on investment of 37.69% and an internal rate of return of 36.1%.

Advisor
Date Range for Data Collection (Start Date)
Date Range for Data Collection (End Date)
Digital Object Identifier
Series name and number
Publication date
2013-04-01
Volume number
Issue number
Publisher
Publisher DOI
Journal Issue
Comments
Recommended citation
Collection