Bijels For Continuous Reactive Separations

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Doctor of Philosophy (PhD)
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Chemical and Biomolecular Engineering
Chemical Engineering
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Di Vitantonio, Giuseppe

Several chemical processes involve the use of mutually immiscible molecules, for example a water-soluble catalyst is used in combination with oil-soluble reagents. There are two possible strategies to run these processes. A mutual solvent can be used to promote mixing of the otherwise immiscible molecules; however, such a system would make the separation of the product challenging. Biphasic systems comprising two immiscible phases can host both polar and apolar species and at the same time allowing separation of molecules of different polarity by simple phase partitioning. Two forms of biphasic reactive separation systems have been studied: emulsion-based and membrane-based systems. However, the efficiency of these systems can be further enhanced. Significantly, all emulsion-based systems comprise a continuous phase and a droplet phase; the discrete nature of the droplets makes the supply or reagent or retrieval of product challenging. Although continuous processing is possible, membrane reactors have limitations in their interfacial area. A recently developed class of soft materials, bicontinuous interfacially jammed emulsion gels or bijels provide opportunity to overcome the shortcomings of emulsions and membrane-based biphasic reactors. Bijels are made by triggering the spinodal decomposition of a homogenous mixture of fluids by co-solvent removal; the three dimensional bicontinuous structure arising from spinodal decomposition has several advantages since both the water and the oil phases are co-continuous and therefore allow for the continuous transport of chemicals throughout its domains and provide a significantly higher water/oil interfacial area than membranes. However several aspects of bijels must be further addressed to enable their application as reactive media. For examples, bijels are fragile; they lose their microscopic and macroscopic structure under mechanical (e.g. flow, agitation) and chemical stresses (e.g. pH change). Moreover, most bijel formulations are unsuitable for system involving biological molecules such as enzymes, as they require surfactants to control nanoparticle wetting properties. This study addresses these shortcomings developing methods to engineer bijels for reactive separation. Reactive separation is successfully demonstrated in these bijels in batch mode. Lastly, for the first time, bijels are used for continuous reactive separation and their performance is compared to membrane-based reactors and simple batch stirred tank reactors.

Daeyeon Lee
Kathleen Stebe
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