Department of Physics Papers

Document Type

Journal Article

Date of this Version

4-3-2009

Comments

Suggested Citation:
Fisher, J.A.N., K. Susumu, M.J. Therien and A.G. Yodh. (2009). "One- and two-photon absorption of highly conjugated multiporphyrin systems in the two-photon Soret transition region." The Journal of Chemical Physics. 130, 134506.

Copyright 2009 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in The Journal of Chemical Physics. and may be found at http://dx.doi.org/10.1063/1.3089795.

Abstract

This study presents a detailed investigation of near-infrared one- and two-photon absorption (TPA) in a series of highly conjugated (porphinato)zinc(II) oligomers (PZnn species), (porphinato)zinc(II)-spacer-(porphinato)zinc(II) (PZn-Sp-PZn) complexes, PZNn structures featuring terminal electron-releasing and -withdrawing substituents, related conjugated arrays in which electron-rich and -poor PZn unites alternate, and benchmark PZn monomers. Broadband TPA cross-section measurements were performed ratiometrically using fluorescein as a reference. Superficially, the measurements indicate very large TPA cross-sections (up to ~ 104 GM; 1 GM = 1 × 10-50 cm4s photon-1) in the two-photon Soret (or B-band) resonance region. However, a more careful analysis of fluorescence as a function of incident photon flux suggests that significant one-photon absorption is present in the same spectral region for all compounds in the series. TPA cross-sections are extracted for the first time for some of these compounds using a model that includes both one-photon absorption and TPA contributions. Resultant TPA cross-sections are ~ 10 GM. The findings suggest that large TPA cross-sections reported in the Soret resonance region of similar compounds might contain significant contributions from one-photon absorption processes.

Date Posted: 06 January 2011

This document has been peer reviewed.