Nature of Viscoelasticity in Lamellar Block Copolymers: Contraction Correlated to Strain Localization

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Polis, D. L.
Ryan, A. J.
Smith, S. D.
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We determined the local strain profile in sheared lamellar block copolymers. A trilayer model, based on elastic brushes separated by viscous interpenetration zones, captures the rheological response of these materials and provides a measure of the relative contributions of elastic versus viscous strain. The elastic chain distortions were evident from a reversible lamellar contraction, as measured from in situ small-angle x-ray scattering. The contraction was directly correlated to the elastic strain from our trilayer model; three distinct diblock copolymers conform to the predicted relationship, thus suggesting universal behavior.

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1999-10-04
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Copyright American Physical Society. Reprinted from Physical Review Letters, Volume 83, Issue 14, October 1999, pages 2861-2864. Publisher URL: http://dx.doi.org/10.1103/PhysRevLett.83.2861
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